Effective Role of Two Layers of Silica in the Performance of Fe3O4@xSiO2@ySiO2@BisPyP-Ni Core-Shell Catalyst for C-C and C-S Coupling Reactions

In this research, a novel core-shell nanocatalyst with silica bi-shell around Fe 3 O 4 and nickel active center, i.e. Fe 3 O 4 @xSiO 2 @ySiO 2 @BisPyP-Ni was synthesized and its characteristics were comprehensively discussed. This nanocatalyst was successfully used to synthesize biaryls (18 examples...

Full description

Saved in:
Bibliographic Details
Published in:SILICON 2024-06, Vol.16 (9), p.3795-3809
Main Authors: Saleh, Ebraheem Abdu Musad, Kassem, Asmaa F., Altalbawy, Farag M. A., Shoja, Sarah Jawad, Bokov, Dmitry Olegovich, Elawady, Ahmed, Al-Rubaye, Ameer H., Saud, Abdulnaser, Al-Mashhadani, Zuhair I., Nejad, Maryam Sadat Ghorayshi
Format: Article
Language:English
Subjects:
Carbon
Catalysts
Chemical reactions
Chemistry
Chemistry and Materials Science
Environmental Chemistry
Ethanol
Inorganic Chemistry
Iron oxides
Lasers
Magnetic cores
Materials Science
Nanoparticles
Natural products
Nickel
Optical Devices
Optics
Palladium
Pharmaceuticals
Photonics
Polymer Sciences
Production lines
Silicon dioxide
Substrates
Sulfur
Synthesis
Citations: Items that this one cites
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:In this research, a novel core-shell nanocatalyst with silica bi-shell around Fe 3 O 4 and nickel active center, i.e. Fe 3 O 4 @xSiO 2 @ySiO 2 @BisPyP-Ni was synthesized and its characteristics were comprehensively discussed. This nanocatalyst was successfully used to synthesize biaryls (18 examples, 15–30 min, 92–98%) and diaryl sulfides (10 examples, 20–140 min, 79–98%) at 80 °C. Excellent performance in speeding up the reaction time, magnetic nature, high porosity, and immobilization of two layers around Fe 3 O 4 are four prominent characteristics of this catalyst. Coating the magnetic core with silica layers led to saving the consumption of the catalyst because this trick leads to the bonding of more organic groups to the substrate, as a result, more nickel enters the mesoporous cavities, and the reaction with a smaller amount of catalyst is finished (in a shorter time). Other advantages of both our production lines are: the ability to recover and reuse the catalyst for up to 8 runs (without a noticeable decrease in its catalytic performance), extensive substrate scope, the employ of commercially accessible materials, simple workup, environmental safety and the heterogeneous nature of the catalyst (by confirming the reusability and hot filtration test results). Graphical Abstract
ISSN:1876-990X
1876-9918
DOI:10.1007/s12633-024-02959-0