Thermal-reductive transformations of carbon dioxide catalyzed by small molecules using earth-abundant elements

In the present review, we summarize the progress for thermal reductive transformations of CO2 catalyzed by small homogeneous catalysts using earth-abundant elements. Three main types of transformations categorized by the use of different reductants（hydrogen, hydrosilanes, and boranes）, in which no C...

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Bibliographic Details
Published in:Science China. Chemistry 2015-10, Vol.58 (10), p.1524-1531
Main Authors: Liu, Muhua, Qin, Tian, Zhang, Qingqing, Fang, Chi, Fu, Yao, Lin, Bo-Lin
Format: Article
Language:English
Subjects:
Carbon dioxide
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Covalent bonds
Mini Reviews
Reducing agents
Thermal transformations
二氧化碳
催化剂
小分子
硼烷
碳热还原
稀土元素
转化
还原剂
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Summary:In the present review, we summarize the progress for thermal reductive transformations of CO2 catalyzed by small homogeneous catalysts using earth-abundant elements. Three main types of transformations categorized by the use of different reductants（hydrogen, hydrosilanes, and boranes）, in which no C–C bond formation is involved, are surveyed.
ISSN:1674-7291
1869-1870
DOI:10.1007/s11426-015-5405-y