Direct Formation of Burkeite in the Geothermal Waters at Vranjska Banja, Serbia

There are no available data about direct burkeite formation on the geothermal waters pipelines in Europe. Data about accompanying minerals of burkeite are also scarce. This mineral has been found in the scale on pipelines of VG-2 and VG-3 boreholes at Vranjska Banja, Serbia. Geothermal waters from t...

Full description

Saved in:
Bibliographic Details
Published in:Natural resources research (New York, N.Y.) N.Y.), 2019-10, Vol.28 (4), p.1259-1267
Main Authors: Todorović, Bratislav Ž., Stojiljković, Dragan T., Pantić, Tanja Petrović, Matović, Branko, Djordjević, Marija Prekajski, Petrović, Sanja M., Stojiljković, Milena S., Stevanović, Miloš M.
Format: Article
Language:English
Subjects:
Boreholes
Calcite
Chemistry and Earth Sciences
Computer Science
Earth and Environmental Science
Earth Sciences
Fossil Fuels (incl. Carbon Capture)
Geography
Geology
Halites
Mathematical Modeling and Industrial Mathematics
Mineral Resources
Minerals
Original Paper
Physics
Pipelines
Qualitative analysis
Quartz
Renewable resources
Scale formation
Sediments
Spectrometry
Statistics for Engineering
Sustainable Development
Temperature
Volcanoes
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:There are no available data about direct burkeite formation on the geothermal waters pipelines in Europe. Data about accompanying minerals of burkeite are also scarce. This mineral has been found in the scale on pipelines of VG-2 and VG-3 boreholes at Vranjska Banja, Serbia. Geothermal waters from these boreholes have temperatures in the range of 103 and 105 °C which classifies them to the warmest waters in the continental Europe. Based on physicochemical and geochemical data, VG-2 and VG-3 geothermal waters can be classified as Na–Alk–SO4Cl type of waters. According to their temperatures, total hardness and pH values, these waters belong to hyperthermal, very soft and moderately alkaline. Calculated LSI (0.4 and 1.7) and RSI (6.5 and 4.8) values indicate their scale formation tendency. Results of the spectrometric scale examination from the pipe deposits provide a clear qualitative and quantitative burkeite characterization with its accompanying minerals. FTIR analysis points to the presence of carbonate (1766, 1458, 877 and 705 cm −1 ) and sulfate bands (1139, 1116 and 617 cm −1 ). Apart from the qualitative analysis, XRD also shows the burkeite mass part in the scale. VG-2 geothermal water contains about 50% of burkeite, which is associated with trona mineral (40%) and smaller amount of halite of about 10%. Burkeite is a dominant phase (> 60%) in VG-3 water, with the presence of a significant halite quantity (> 35%) and a minor calcite quantity (2%).
ISSN:1520-7439
1573-8981
DOI:10.1007/s11053-019-09455-y