Spectral, optical, and thermal analyses of tris-(thiourea) zinc sulfate nonlinear optical crystals

The current research uses a slow evaporation procedure to create Thiourea Zinc sulfate (TTZS), crystal. Powder-XRD, Fourier transforms infrared (FTIR), UV-visible, and thermal and second harmonic generation have all been used to describe the TTZS. The TTZS crystallized in an orthorhombic form, based...

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Bibliographic Details
Published in:Ferroelectrics 2023-01, Vol.615 (1), p.167-175
Main Authors: Albert, Helen Merina, Jemima, T., Alosious Gonsago, C.
Format: Article
Language:English
Subjects:
Crystal growth
Crystallization
Crystals
Differential thermal analysis
Evaporation
Fourier transforms
FTIR
Functional groups
Infrared spectroscopy
Nonlinear optics
Second harmonic generation
Sulfates
TG/DTA
Thermal response
Thioureas
Ultraviolet spectroscopy
Vibration mode
Visible spectrum
XRD
Zinc
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Summary:The current research uses a slow evaporation procedure to create Thiourea Zinc sulfate (TTZS), crystal. Powder-XRD, Fourier transforms infrared (FTIR), UV-visible, and thermal and second harmonic generation have all been used to describe the TTZS. The TTZS crystallized in an orthorhombic form, based on XRD. The functional groups and vibrational modes were validated by FTIR. The transparency over the UV-visible spectrum has been confirmed by UV spectroscopy. The SHG test illustrates the creation of second harmonic signals from samples. The thermal response of TTZS is shown by the TG/DTA. The findings suggest that TTZS might be a potential NLO material.
ISSN:0015-0193
1563-5112
DOI:10.1080/00150193.2023.2243560