Direct Cross-Dehydrogenative C–N-Coupling of Phenanthridine with 1H-Benzotriazole

A procedure has been developed for the direct C sp 2–H functionalization of phenanthridine with a 1 H -benzotriazole residue in the presence of Selectfluor® to build up C sp 2–N bond. The procedure makes it possible to synthesize 6-(1 H -benzotriazol-1-yl)phenanthridine in one step using commerciall...

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Bibliographic Details
Published in:Russian journal of organic chemistry 2023-07, Vol.59 (7), p.1255-1259
Main Authors: Akulov, A. A., Pershin, A. A., Kopchuk, D. S., Varaksin, M. V., Zyryanov, G. V., Chupakhin, O. N.
Format: Article
Language:English
Subjects:
Benzotriazole
Chemistry
Chemistry and Materials Science
Dehydrogenation
Organic Chemistry
Reagents
Substrates
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Summary:A procedure has been developed for the direct C sp 2–H functionalization of phenanthridine with a 1 H -benzotriazole residue in the presence of Selectfluor® to build up C sp 2–N bond. The procedure makes it possible to synthesize 6-(1 H -benzotriazol-1-yl)phenanthridine in one step using commercially available starting materials and reagents. The product is an important substrate for further chemical transformations.
ISSN:1070-4280
1608-3393
DOI:10.1134/S1070428023070199