Thermal storage properties of Mg with synergistic effect of LaNi and TiH2

The effect of LaNi and Ti on thermal storage properties of MgH 2 was investigated. The thermal storage performances of Mg are significantly improved by adding LaNi and Ti. The pressure–composition–temperature (PCT) curves indicate that the formation enthalpy for Mg-15 wt%Ti-5 wt%LaNi sample is 73.00...

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Bibliographic Details
Published in:Rare metals 2023-05, Vol.42 (5), p.1743-1751
Main Authors: Wan, Qi, Jiang, Li-Jun, Li, Zhi-Nian, Yang, Yang, Wang, Shu-Mao, Liu, Xiao-Peng
Format: Article
Language:English
Subjects:
Biomaterials
Chemistry and Materials Science
Energy
Enthalpy
Heat storage
Materials Engineering
Materials Science
Metal hydrides
Metallic Materials
Nanoscale Science and Technology
Physical Chemistry
Synergistic effect
Thermal storage
Titanium compounds
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Summary:The effect of LaNi and Ti on thermal storage properties of MgH 2 was investigated. The thermal storage performances of Mg are significantly improved by adding LaNi and Ti. The pressure–composition–temperature (PCT) curves indicate that the formation enthalpy for Mg-15 wt%Ti-5 wt%LaNi sample is 73.00 kJ·mol −1 , which approaches to the theoretical values of pure MgH 2 . The isothermal measurement indicates that, for the Mg-15 wt%Ti-5 wt%LaNi, the first absorption reaction fraction within 2 min is 93.77%, increasing by 0.32%, 0.24% and 0.08% compared with those for Mg, Mg-5 wt%LaNi and Mg-15 wt%Ti, respectively. The first desorption reaction fraction within 2 min is 73.18%, increasing by 55.91%, 9.79% and 8.12% compared with those for Mg, Mg-5 wt%LaNi and Mg-15 wt%Ti, respectively. Moreover, Mg-15 wt%Ti-5 wt%LaNi has the best cyclic stability in all the samples. The thermal storage performances of Mg by adding both LaNi and Ti are improved mainly ascribed to synergistic effect of in situ formed La 4 H 12.19 , Mg 2 NiH 4 , H 0.3 Mg 2 Ni and TiH 2 particles during cyclic process. The above analysis demonstrates that Mg-15 wt%Ti-5 wt%LaNi is suitable for using as a heat storage material.
ISSN:1001-0521
1867-7185
DOI:10.1007/s12598-016-0858-5