Vapor Equilibrium Data for the Binary Mixtures of Dimethyl Carbonate and Ethyl Methyl Carbonate in Compressed Carbon Dioxide

Phase equilibrium data ( p , T , y ) for the binary systems of carbon dioxide + dimethyl carbonate and carbon dioxide + ethyl methyl carbonate were obtained. All systems were measured for isotherms ranging from 298.2 K to 328.2 K with pressure ranging between 0.13 MPa and 10.6 MPa. A static equilibr...

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Bibliographic Details
Published in:International journal of thermophysics 2023-06, Vol.44 (6), Article 86
Main Authors: Jethwa, Shiva J., Román-Ramírez, Luis A., Anderson, Paul A., Leeke, Gary A.
Format: Article
Language:English
Subjects:
Binary mixtures
Binary systems
Carbon dioxide
Classical Mechanics
Condensed Matter Physics
Equations of state
Geophysics
Industrial Chemistry/Chemical Engineering
Mixing rules
Phase equilibria
Physical Chemistry
Physics
Physics and Astronomy
Static equilibrium
Thermodynamics
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Summary:Phase equilibrium data ( p , T , y ) for the binary systems of carbon dioxide + dimethyl carbonate and carbon dioxide + ethyl methyl carbonate were obtained. All systems were measured for isotherms ranging from 298.2 K to 328.2 K with pressure ranging between 0.13 MPa and 10.6 MPa. A static equilibrium technique was established with samples quantified using an offline method. The results were modeled using the Peng–Robinson equation of state with van der Waals one-fluid mixing rules. Graphical Abstract
ISSN:0195-928X
1572-9567
DOI:10.1007/s10765-023-03186-2