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Pristine Metal–Organic Frameworks and their Composites for Renewable Hydrogen Energy Applications
Metal–organic frameworks (MOFs) have emerged as ideal multifunctional platforms for renewable hydrogen (H2) energy applications owing to their tunable chemical compositions and structures and high porosity. Their advanced component species and porous structure contribute greatly to the enhanced acti...
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Published in: | Advanced functional materials 2023-02, Vol.33 (8), p.n/a |
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Main Authors: | , , , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | Metal–organic frameworks (MOFs) have emerged as ideal multifunctional platforms for renewable hydrogen (H2) energy applications owing to their tunable chemical compositions and structures and high porosity. Their advanced component species and porous structure contribute greatly to the enhanced activity, electrical conductivity, photo response, charge‐hole separation efficiency, and structural stability of MOF materials, which are promising for practical H2 economy. In this review, we mainly introduce design strategies for the enhancement of electro‐/photochemical behaviors or adsorption performance of porous MOF materials for H2 production, storage, and utilization from compositional perspective. Following these engineering strategies, the correlation between composition and property‐structure‐performance of pristine MOFs and their composite with advanced components is illustrated. Finally, challenges and directions of future development of related MOFs and MOF composites for H2 economy are provided.
In this review article, engineering strategies are exhaustively analyzed for the enhancement of electro‐/photochemical behaviors or adsorption performance of pristine MOFs and their composites for hydrogen energy applications from compositional perspective. Furthermore, challenges and future research directions in this emerging area of MOFs and their composites for H2 economy are provided. |
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ISSN: | 1616-301X 1616-3028 |
DOI: | 10.1002/adfm.202203224 |