Modification of Structural-Textural Properties of Sulfide Minerals at Polymetallic Concentrate Leaching with Sulfuric Acid and Hydrogen Peroxide Solutions

This paper examines the effects of structural-textural characteristics of sulfide minerals on their leaching from polymetallic concentrates with sulfuric acid and hydrogen peroxide solutions. The polymetallic concentrate was obtained by flotation of polymetallic ore from the Rudnik deposit in Serbia...

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Published in:Russian journal of non-ferrous metals 2022-10, Vol.63 (5), p.457-472
Main Authors: Sokić, Miroslav, Stojanović, Jovica, Marković, Branislav, Kamberović, Željko, Gajić, Nataša, Radosavljević-Mihajlović, Ana, Milojkov, Dušan
Format: Article
Language:English
Subjects:
Chalcopyrite
Chemistry and Materials Science
Flotation
Free form
Galena
Grains
Hydrogen peroxide
Leaching
Materials Science
Metallic Materials
Mineral Processing of Nonferrous Metals
Mineralogy
Minerals
Pyrrhotite
Qualitative analysis
Residues
Scanning electron microscopy
Sulfur
Sulfuric acid
X-ray diffraction
Zincblende
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Summary:This paper examines the effects of structural-textural characteristics of sulfide minerals on their leaching from polymetallic concentrates with sulfuric acid and hydrogen peroxide solutions. The polymetallic concentrate was obtained by flotation of polymetallic ore from the Rudnik deposit in Serbia. X-ray diffraction (XRD), qualitative and quantitative mineralogical, scanning electron microscopy (SEM/EDX), and chemical analyses were used to characterize the polymetallic concentrate and leach residue. The polymetallic concentrate contained chalcopyrite, galena, sphalerite, pyrrhotite, and quartz. The total content of sulfide minerals was 69.5%, and the occurrence of free sulfide mineral grains was about 60.9%. The comprehensive thermodynamic analysis was done by HSC Chemistry ® package 9.9.2.3 to determine optimal experimental leaching conditions. Chalcopyrite, sphalerite, and pyrrhotite oxidized during leaching, and dissolution occurred. The oxidized galena remains in the solid residual as insoluble anglesite. Also, elemental sulfur and unleached minerals of copper, zinc, and iron were found in the leach residues. It was found that the structural assembly of sulfide minerals in the leach residue is very favorable and that undissolved sulfide grains are primarily present in free form. Accordingly, there was no reason to reduce the leaching rate with time. The presence of elemental sulfur and anglesite formed in the leaching process and precipitated on the surface of mineral grains was confirmed by XRD, quantitative and qualitative mineralogical analysis, and SEM/EDX.
ISSN:1067-8212
1934-970X
DOI:10.3103/S1067821222050091