Transport properties and phase diagrams of FeSe1−xSx (0 ≤ x ≤ 1) single crystals

Based on the high quality FeSe1−xSx (0 ≤ x ≤ 1) single crystals synthesized via a hydrothermal method, we carried out systematic measurement of the normal state magnetoresistance and Hall effect. Through the maximum entropy mobility spectrum analysis (MEMSA), we investigate the evolution of mobility...

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Bibliographic Details
Published in:Journal of alloys and compounds 2022-10, Vol.919, p.1, Article 165760
Main Authors: Liu, W.H., Yi, X.L., Li, W.C., Xing, X.Z., Zhao, H.J., Xu, M.X., Shi, Z.X.
Format: Article
Language:English
Subjects:
Anions
Carrier density
FeSe1−xSx
First principles
Hall effect
Hydrothermal crystal growth
Magnetoresistance
Magnetoresistivity
Mathematical analysis
Maximum entropy
Phase diagram
Phase diagrams
Phases
Single crystals
Spectrum analysis
Superconductivity
Superconductors
Transport properties
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Summary:Based on the high quality FeSe1−xSx (0 ≤ x ≤ 1) single crystals synthesized via a hydrothermal method, we carried out systematic measurement of the normal state magnetoresistance and Hall effect. Through the maximum entropy mobility spectrum analysis (MEMSA), we investigate the evolution of mobility spectrum, which reflects the multi-band structures for different doping content x and temperature T. The relationships between Tc and carrier properties calculated by MEMSA, as well as bond angles and anion height calculated by first-principle method are investigated. Nonlinear to linear transition of Hall resistivity(ρxy(B)) is mainly attributed to the decreasing mobilities and merging of mobility peaks with the reductive x or increasing T. The relationship between Tc and carrier density n show weak interaction for the orthogonal phases when x ≤ 0.2, but nearly positive correlation for the tetragonal phases when x > 0.2. Bond angle as well as the Se/S anion height change almost linearly with x within the tetragonal phases, and the V-shaped relationships with Tc indicate that structural factors play a key role in the regulation of superconductivity. Our researches are helpful for understanding the multi-band and complex phase diagram of iron-based superconductors. •We systematically measured magnetoresistance and Hall resistivity of FeSe1−xSx (0 ≤ x ≤ 1) single crystals.•Nonlinear to linear transition of Hall resistivity is mainly due to decreasing mobilities and merging of mobility peaks.•The bond angle and Se/S anion height both show V-shaped relationships with Tc.•Structural factors play a key role in the regulation of superconductivity in iron-based superconductors.
ISSN:0925-8388
1873-4669
DOI:10.1016/j.jallcom.2022.165760