Mercury(II) chloride in the synthesis of nido-carborane derivatives with B-N, B-O, and B-S bonds

The use of mercury(II) chloride for the synthesis of nido -carborane derivatives with B-O, B-N, and B-S bonds was considered. The involvement of HgCl 2 allows one to selectively obtain symmetrically substituted nido -carborane derivatives in high yields. The resulting derivatives can undergo various...

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Bibliographic Details
Published in:Russian chemical bulletin 2022, Vol.71 (1), p.91-101
Main Authors: Stogniy, M. Yu, Anufriev, S. A., Bogdanova, E. V., Sivaev, I. B., Bregadze, V. I.
Format: Article
Language:English
Subjects:
Carborane
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Chlorides
Crystals
Dimethyl sulfide
Full Articles
Inorganic Chemistry
Mercury compounds
Organic Chemistry
Single crystals
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Summary:The use of mercury(II) chloride for the synthesis of nido -carborane derivatives with B-O, B-N, and B-S bonds was considered. The involvement of HgCl 2 allows one to selectively obtain symmetrically substituted nido -carborane derivatives in high yields. The resulting derivatives can undergo various modification reactions of the organic substituent or be used in the synthesis of metallacarboranes. The structure of the 8,8′-di(dimethyl sulfide)-6,6′-diphenyl derivative of iron(II) bis(dicarbollide) was determined by single-crystal X-ray diffraction.
ISSN:1066-5285
1573-9171
DOI:10.1007/s11172-022-3381-x