FeS–Ga2S3–In2S3 System

Phase equilibria in the FeS–Ga 2 S 3 –In 2 S 3 system were investigated by differential thermal analysis and X-ray powder diffraction analysis. A number of polythermal sections, the isothermal sections at 900 and 1070 K, and the projection of the liquidus surface of the phase diagram were constructe...

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Bibliographic Details
Published in:Russian journal of inorganic chemistry 2021-10, Vol.66 (10), p.1533-1543
Main Authors: Mammadov, F. M., Babanly, D. M., Amiraslanov, I. R., Tagiev, D. B., Babanly, M. B.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Crystallization
Differential thermal analysis
Gallium sesquisulfide
Inorganic Chemistry
Liquidus
Magnetic materials
Phase diagrams
Phase equilibria
Physicochemical Analysis of Inorganic Systems
Solid solutions
X ray powder diffraction
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Summary:Phase equilibria in the FeS–Ga 2 S 3 –In 2 S 3 system were investigated by differential thermal analysis and X-ray powder diffraction analysis. A number of polythermal sections, the isothermal sections at 900 and 1070 K, and the projection of the liquidus surface of the phase diagram were constructed. It was determined that this system is quasi-ternary, and that the liquidus surface consists of the fields of primary crystallization of six phases. Wide regions of solid solutions based on binary and ternary compounds (FeGa 2 S 4 and FeIn 2 S 4 ) were found, which are of interest as magnetic materials.
ISSN:0036-0236
1531-8613
DOI:10.1134/S0036023621100090