Design of 7-substituted 3-azabicyclo[3.3.1]non-6-enes based on allylboron-acetylene condensation

An efficient synthesis of 7-substituted 3-azabicyclo[3.3.1]non-6-enes from available 3-borabicyclo[3.3.1]non-6-enes, the products of allylboron-acetylene condensation, was developed. The terminal alkynes with nitrogen-containing substituents were involved for the first time into the reaction with tr...

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Bibliographic Details
Published in:Russian chemical bulletin 2021-10, Vol.70 (10), p.1987-1993
Main Authors: Iurenkov, M. V., Potapova, T. V., Baranin, S. V., Bubnov, Yu. N.
Format: Article
Language:English
Subjects:
Acetylene
Alkynes
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Condensates
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Inorganic Chemistry
Organic Chemistry
Substitutes
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Summary:An efficient synthesis of 7-substituted 3-azabicyclo[3.3.1]non-6-enes from available 3-borabicyclo[3.3.1]non-6-enes, the products of allylboron-acetylene condensation, was developed. The terminal alkynes with nitrogen-containing substituents were involved for the first time into the reaction with triallylborane.
ISSN:1066-5285
1573-9171
DOI:10.1007/s11172-021-3306-0