Synthesis, characterization and application development of ordered mesoporous silica in wastewater remediation

This study describes the total removal of multiple heavy metal ions from wastewater using organo-functionalized ordered mesoporous silica MCM-41. Hydrothermal synthesis of siliceous MCM-41 was done using sodium silicate as precursor through a new cost-effective and environmentally friendly silica pr...

Full description

Saved in:
Bibliographic Details
Published in:Journal of porous materials 2021-12, Vol.28 (6), p.1867-1879
Main Authors: Lolage, Mayura, Chaskar, Manohar, Ghosh, Anirban
Format: Article
Language:English
Subjects:
Catalysis
Characterization and Evaluation of Materials
Chemistry
Chemistry and Materials Science
Emission analysis
Heavy metals
Ion adsorption
Ions
Metal ions
Physical Chemistry
Room temperature
Silicon dioxide
Sodium silicates
Wastewater treatment
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:This study describes the total removal of multiple heavy metal ions from wastewater using organo-functionalized ordered mesoporous silica MCM-41. Hydrothermal synthesis of siliceous MCM-41 was done using sodium silicate as precursor through a new cost-effective and environmentally friendly silica precipitation method. Functionalization of siliceous MCM-41 by thiol-containing organosilane was done through a post-synthesis grafting route at room temperature. Physicochemical characterization reveals that the resultant materials have highly ordered hexagonal mesoporous structure and high BET surface area in the range of 1000‒1200 m 2 /g, before and after organo-functionalization. The organo-functionalized mesoporous materials have been applied for adsorption of a mixture of heavy metal ions from wastewater at room temperature, where the heavy metal ions covalently bind non-selectively with the pendant thiol moieties inside the mesopores. As envisaged from elemental analyses using atomic emission spectroscopy, high efficiency of heavy metal ion adsorption from wastewater was observed, which was significantly better than that of standard adsorbents.
ISSN:1380-2224
1573-4854
DOI:10.1007/s10934-021-01126-9