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Effect of Crystallinity of Synthetic Graphite on Electrochemical Potassium Intercalation into Graphite
An effect of crystallinity of graphite on formation of graphite intercalation compounds (GICs) and reversibility in K cells was studied by comparing that in Li cells. Though high reversible capacities and coulombic efficiencies of graphite electrodes in K cells were achieved during initial cycles re...
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Published in: | Denki kagaku oyobi kōgyō butsuri kagaku 2021/09/05, Vol.89(5), pp.433-438 |
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Main Authors: | , , , , , , , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | An effect of crystallinity of graphite on formation of graphite intercalation compounds (GICs) and reversibility in K cells was studied by comparing that in Li cells. Though high reversible capacities and coulombic efficiencies of graphite electrodes in K cells were achieved during initial cycles regardless of the crystallinity, high crystallinity graphite demonstrated less potential-hysteresis and superior capacity retention to low crystallinity graphite. Operando XRD measurement confirmed similar staging process of K-GICs for both graphite, however, high crystallinity graphite transformed into higher crystallinity of K-GIC as well as higher reversibility of potassium de-/intercalation than low crystallinity graphite. A turbostratic disorder in low crystallinity graphite led to redox-potential split and lower crystalline K-GIC and potassium-extracted graphite. Thus, the crystallinity of graphite, which includes coherence length and the degree of random stacking, is found to be a predominant factor for highly reversible potassium intercalation, which differs from the lithium case. We concluded that the high crystallinity is of importance for the application of graphite to long-life potassium-ion batteries. |
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ISSN: | 1344-3542 2186-2451 |
DOI: | 10.5796/electrochemistry.21-00062 |