Monolayer grafting of APTES modified graphene oxide on silica coated magnetite: Synthesis, characterization and application in heavy oil removal

Petroleum industries have been creating negative environmental and ecological impacts due to the formation of oilfield produced water (OPW) during refining processes. Graphene oxide (GO) as a chemical demulsifier was found non-recyclable; hence, it could cause environmental pollution. Thus, magnetic...

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Bibliographic Details
Published in:IOP conference series. Materials Science and Engineering 2020-10, Vol.943 (1), p.12023
Main Authors: Ye Wong, Chung, Shi Tan, Inn, Chee Yew Foo, Henry, Kuok Ho Tang, Daniel, Hua Tan, Yie, Fong Yeong, Yin, Kee Lam, Man
Format: Article
Language:English
Subjects:
Graphene
Iron oxides
Magnetic properties
Magnetic separation
Magnetite
Nanoparticles
Oil field equipment
Oil fields
Silicon dioxide
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Summary:Petroleum industries have been creating negative environmental and ecological impacts due to the formation of oilfield produced water (OPW) during refining processes. Graphene oxide (GO) as a chemical demulsifier was found non-recyclable; hence, it could cause environmental pollution. Thus, magnetic graphene oxide (M-GO) was proposed to prevent any possible contamination. In this work, GO, and M-GO were successfully synthesized and the produced M-GO composites were found coated with silica-coated magnetite (Fe3O4@SiO2) nanoparticles. As such, they possess excellent superparamagnetic properties. The demulsification tests demonstrated that 0.25 wt% of M-GO aqueous suspension achieved 98.53% of demulsification efficiency on the as-prepared crude oil-in-water emulsion, which was more superior than GO as the suspending oil floccules attached to M-GO can be separated effectively using magnetic separation. The optimizations of the demulsification process were conducted, and significant findings were included as the major novelty of this work. The recycling tests have proven that M-GO can be reused to perform demulsification effectively for ten times. Despite being able to reduce the demulsification costs in the industry, this research suggests that the excellent properties of M-GO can minimize the risk of polluting the environment due to leakage of demulsifier through the application of magnetic separation.
ISSN:1757-8981
1757-899X
DOI:10.1088/1757-899X/943/1/012023