2-[1-(Dimethylamino)ethyl]ferrocenylphosphinic acid as an organocatalyst of Michael and Friedel—Crafts reactions

Racemic 2-[1-(dimethylamino)ethyl]ferrocenylphosphinic acid was tested as an organocatalyst in the Michael and Friedel—Crafts reactions. The use of this zwitterion provides 78% conversion in the Michael reaction between cyclohexanone and β-nitrostyrene, and 84% conversion in the Friedel—Crafts react...

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Bibliographic Details
Published in:Russian chemical bulletin 2021-07, Vol.70 (7), p.1415-1417
Main Authors: Shekurov, R. P., Gilmanova, L. H., Zagidullin, A. A., Miluykov, V. A.
Format: Article
Language:English
Subjects:
Brief Communications
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Conversion
Cyclohexanone
Friedel-Crafts reaction
Inorganic Chemistry
Michael reaction
Organic Chemistry
Zwitterions
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Summary:Racemic 2-[1-(dimethylamino)ethyl]ferrocenylphosphinic acid was tested as an organocatalyst in the Michael and Friedel—Crafts reactions. The use of this zwitterion provides 78% conversion in the Michael reaction between cyclohexanone and β-nitrostyrene, and 84% conversion in the Friedel—Crafts reaction between β-nitrostyrene and indole.
ISSN:1066-5285
1573-9171
DOI:10.1007/s11172-021-3233-0