Design of zinc vanadate (Zn3V2O8)/nitrogen doped multiwall carbon nanotubes (N-MWCNT) towards supercapacitor electrode applications

An electrochemically active composite material consisting of zinc vanadate (Zn3V2O8) and nitrogen doped multi wall carbon nanotubes (N-MWNCT) was prepared using simple hydrothermal procedure. This attractive composite material was exploited as an electrode for the supercapacitor application. The mul...

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Bibliographic Details
Published in:Journal of electroanalytical chemistry (Lausanne, Switzerland) Switzerland), 2021-01, Vol.881, p.114936, Article 114936
Main Authors: Suganya, B., Maruthamuthu, S., Chandrasekaran, J., Saravanakumar, B., Vijayakumar, E., Marnadu, R., Al-Enizi, Abdullah M., Ubaidullah, Mohd
Format: Article
Language:English
Subjects:
Charge transfer
Composite materials
Energy storage
K+ ions
Multi wall carbon nanotubes
MWCNT
Neutral electrolyte
Nitrogen
Oxidation
Potassium sulfate
Redox reactions
Supercapacitor
Supercapacitors
Vanadates
Zinc
Zn3V2O8
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Summary:An electrochemically active composite material consisting of zinc vanadate (Zn3V2O8) and nitrogen doped multi wall carbon nanotubes (N-MWNCT) was prepared using simple hydrothermal procedure. This attractive composite material was exploited as an electrode for the supercapacitor application. The multiple oxidation states of vanadium and stable zinc rendered wide range of redox reaction with MWCNT which was explored with K2SO4 neutral electrolyte. The electron microscopic analysis along with XRD and XPS confirmed the formation of ternary composite. The unique combination of Zn3V2O8 and N-MWNCT showed a specific capacitance of 403 F g−1 with better stability of 79% for 5000 cycles. The presence of N-MWCNT enhanced the performance of the ZVC composite by providing structural support which significantly reduced the charge transfer resistance Rct (1.3 Ω) and series resistance Rs (1.8 Ω) by providing synergetic effects. The results have demonstrated the potential scope of ZVC for the energy storage device. [Display omitted] •Electrochemically active composite of zinc vanadate (Zn3V2O8) and (N-MWNCT) was prepared using hydrothermal procedure.•Electron microscopic analysis along with XRD and XPS confirmed the formation of ternary composite.•The unique combination of Zn3V2O8@MWNCT (ZVC) recorded a specific capacitance of 403 F g-1 which is 89% higher than bare Zn3V2O8.•Considerable reduction in charge transfer resistance Rct (1.3) and series resistance Rs (1.8) for ZVC composites.•ZVC based asymmetric supercapacitor demonstrated better cyclic stability of 81% for 5000 cycles.
ISSN:1572-6657
1873-2569
DOI:10.1016/j.jelechem.2020.114936