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On the correlation of the magnetic properties with the structural parameters in Fe-doped europium chromite
In the present work, the dynamics of the spins and the structural parameters of thermal treated samples of Eu1−xFexCrO3 (x = 0, 0.1 and 0.2) were investigated. The ac-magnetic susceptibility (χac) was measured near TN for frequencies (f) in the range 10 - 104 Hz, magnitude of the ac magnetic field o...
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Published in: | AIP advances 2021-03, Vol.11 (3), p.035205-035205-5 |
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Main Authors: | , , , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites |
Online Access: | Get full text |
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Summary: | In the present work, the dynamics of the spins and the structural parameters of thermal treated samples of Eu1−xFexCrO3 (x = 0, 0.1 and 0.2) were investigated. The ac-magnetic susceptibility (χac) was measured near TN for frequencies (f) in the range 10 - 104 Hz, magnitude of the ac magnetic field of 10 Oe and for 5 ≤ T ≤ 300 K. X-ray diffraction data were used for determining the lattice parameters and the bonding angle θB (Cr– O(2) – Cr) for 100 ≤ T ≤ 300 K. The maximum in χac was found to shift to higher values of T for increasing values of f. The Vogel-Fulcher law was used for analyzing χac yielding values for the characteristic relaxation time τ0, activation energy Ea/kB and glassy temperature TG, respectively, in the ranges 2.10 - 3.96 ps, 46.5 - 47.2 K and 169.9 -176.1 K. The super-exchange parameter J∼cos4180−θB/2/d7, where d is the length of the bound Cr-O(2), was also obtained yielding a good correlation with the corresponding values of TN. |
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ISSN: | 2158-3226 2158-3226 |
DOI: | 10.1063/9.0000010 |