Palladium Nanoparticles in Hypercrosslinked Polystyrene: Synthesis and Application in the Hydrogenation of Arenes

A novel method for incorporation of palladium nanoparticles into a porous hypercrosslinked polystyrene matrix has been developed. The composite obtained by reduction of [Pd(π-allyl)Cl] 2 with hydrogen in supercritical CO 2 shows high catalytic activity in the hydrogenation of benzene and can be used...

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Bibliographic Details
Published in:Petroleum chemistry 2021, Vol.61 (1), p.76-80
Main Authors: Lyubimov, S. E., Zvinchuk, A. A., Korlyukov, A. A., Davankov, V. A., Parenago, O. P.
Format: Article
Language:English
Subjects:
Aromatic compounds
Benzene
Catalytic activity
Chemistry
Chemistry and Materials Science
Cyclohexane
Hydrogenation
Industrial Chemistry/Chemical Engineering
Nanoparticles
Palladium
Polystyrene
Polystyrene resins
Porous media
Toluene
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Summary:A novel method for incorporation of palladium nanoparticles into a porous hypercrosslinked polystyrene matrix has been developed. The composite obtained by reduction of [Pd(π-allyl)Cl] 2 with hydrogen in supercritical CO 2 shows high catalytic activity in the hydrogenation of benzene and can be used twelve (12) times in a row without any decrease in conversion rate. The catalyst is also suitable for quantitative hydrogenation of toluene, tetralin and phenol. The obtained catalytic system is compared with the palladium composite synthesized by a conventional method based on hypercrosslinked polystyrene.
ISSN:0965-5441
1555-6239
DOI:10.1134/S0965544121010084