Camps Reaction and Related Cyclizations

The review presents analysis of the literature on the intramolecular cyclization of N -(2-acylaryl)amides, known as the Camps reaction, as well as close analogs of these compounds, N -(3-oxoalkenyl)- and N -(3-oxoalkyl)amides, which contain an amide and a carbonyl groups and react by the aldol–croto...

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Bibliographic Details
Published in:Russian journal of organic chemistry 2020-12, Vol.56 (11), p.1863-1892
Main Authors: Fisyuk, A. S., Kostyuchenko, A. S., Goncharov, D. S.
Format: Article
Language:English
Subjects:
Aldehydes
Amides
Carbonyl groups
Carbonyls
Chemistry
Chemistry and Materials Science
Organic Chemistry
Quinoline
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Summary:The review presents analysis of the literature on the intramolecular cyclization of N -(2-acylaryl)amides, known as the Camps reaction, as well as close analogs of these compounds, N -(3-oxoalkenyl)- and N -(3-oxoalkyl)amides, which contain an amide and a carbonyl groups and react by the aldol–crotonic type. The potential, limitations, and regularities of these reactions leading to quinoline-2(1 H )-ones, quinoline-4(1 H )-ones, pyridin-2-ones, pyridin-4-ones, as well as their hydrogenated derivatives are highlighted.
ISSN:1070-4280
1608-3393
DOI:10.1134/S1070428020110019