Thionylimido Complexes

An improved route to d‐block and main group NSO complexes is presented including the synthesis of the first antimony(V) complexes, (Ar3Sb(NSO)2), and copper examples [CuBipy(PPh3)NSO]. The structures of eight complexes are reported. The observed variation in M–N–S bond angles is due to the combinati...

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Bibliographic Details
Published in:Zeitschrift für anorganische und allgemeine Chemie (1950) 2020-11, Vol.646 (22), p.1795-1798
Main Authors: McGeachie, Liam J. R., Carpenter‐Warren, Cameron L., Cordes, David B., Bühl, Michael, Gray, Steven J., Hua, Guoxiong, Slawin, Alexandra M. Z., Woollins, J. Derek
Format: Article
Language:English
Subjects:
Antimony
Antimony complex
Metal bonding
Thiazate
Thionylimide
X‐ray diffraction
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Summary:An improved route to d‐block and main group NSO complexes is presented including the synthesis of the first antimony(V) complexes, (Ar3Sb(NSO)2), and copper examples [CuBipy(PPh3)NSO]. The structures of eight complexes are reported. The observed variation in M–N–S bond angles is due to the combination of orbital overlap (ligand‐to‐metal bonding) and the degree of ionicity of the bonding.
ISSN:0044-2313
1521-3749
DOI:10.1002/zaac.202000238