n‐Alkanes and PAHs in the Southeastern Tibetan Plateau: Characteristics and Correlations With Brown Carbon Light Absorption

The samples of atmospheric total suspended particle (TSP) were obtained at the remote Tibetan site (named Lulang) from November 2015 to November 2016. The seasonal characteristics of n‐alkanes, polycyclic aromatic hydrocarbons (PAHs) variations, and their correlations to brown carbon (BrC) light abs...

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Bibliographic Details
Published in:Journal of geophysical research. Atmospheres 2020-10, Vol.125 (19), p.n/a
Main Authors: Zhu, Chong‐Shu, Li, Li‐Juan, Huang, Hong, Dai, Wen‐Ting, Lei, Ya‐Li, Qu, Yao, Huang, Ru‐Jin, Wang, Qi‐Yuan, Shen, Zhen‐Xing, Cao, Jun‐Ji
Format: Article
Language:English
Subjects:
Absorption
Absorption coefficient
Absorptivity
Alkanes
Aromatic compounds
Aromatic hydrocarbons
brown carbon
Carbon
Correlation
Correlation analysis
Electromagnetic absorption
Geophysics
Light absorption
n‐alkanes
PAHs
Photochemistry
Polycyclic aromatic hydrocarbons
Seasons
the Tibetan Plateau
Winter
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Summary:The samples of atmospheric total suspended particle (TSP) were obtained at the remote Tibetan site (named Lulang) from November 2015 to November 2016. The seasonal characteristics of n‐alkanes, polycyclic aromatic hydrocarbons (PAHs) variations, and their correlations to brown carbon (BrC) light absorption in TSP were investigated. Elevated TSP n‐alkanes and PAHs levels were observed in winter (2.8 and 10 times higher than in monsoon, respectively), largely due to the seasonal contributions of wintertime home heating and long‐range transport. The total‐PAHs was found to correlate strongly with the methanol‐soluble BrC (MeS‐BrC) light absorption coefficient (babs) (R = 0.80) compared to water‐soluble BrC (WS‐BrC) (R = 0.70) at 365 nm. The BrC solar absorptions percentages to those of element carbon (EC) in the range of ultraviolet (300–400 nm) were high in both winter and premonsoon seasons, which can affect the vulnerable environmental radiative balance and atmospheric photochemistry. Key Points The seasonal characteristics of n‐alkanes and polycyclic aromatic hydrocarbons were investigated The total‐PAHs were found to correlate strongly with the light absorption coefficient of MeS‐BrC compared to WS‐BrC at 365 nm The fractional solar absorptions by BrC relative to EC in the ultraviolet range were significant in winter and premonsoon seasons
ISSN:2169-897X
2169-8996
DOI:10.1029/2020JD032666