Coordination chemistry of anticrowns. Synthesis and structure of the binuclear complex of perfluorinated three-mercury anticrown (o-F6Hg)3 with 1,2-dichloroethane

The reaction of perfluorinated three-mercury anticrown ( o -C 6 F 4 Hg) 3 ( 1 ) with 1,2-dichloroethane (DCE) affords the complex {[( o -C 6 F 4 Hg) 3 ] 2 (ClCH 2 CH 2 Cl)}( 2 ) containing two anticrown molecules per DCE molecule. According to the X-ray diffraction data, the DCE molecule in complex...

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Bibliographic Details
Published in:Russian chemical bulletin 2020-06, Vol.69 (6), p.1092-1095
Main Authors: Tugashov, K. I., Yunusov, S. M., Kalyuzhnaya, E. S., Dolgushin, F. M., Tikhonova, I. A., Shur, V. B.
Format: Article
Language:English
Subjects:
Chemical synthesis
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Chlorine
Dichloroethane
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Inorganic Chemistry
Mercury (metal)
Organic Chemistry
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Summary:The reaction of perfluorinated three-mercury anticrown ( o -C 6 F 4 Hg) 3 ( 1 ) with 1,2-dichloroethane (DCE) affords the complex {[( o -C 6 F 4 Hg) 3 ] 2 (ClCH 2 CH 2 Cl)}( 2 ) containing two anticrown molecules per DCE molecule. According to the X-ray diffraction data, the DCE molecule in complex 2 acts as a bridge between molecules 1 , each DCE chlorine atom being coordinated to a single mercury center of the neighboring anticrown molecules.
ISSN:1066-5285
1573-9171
DOI:10.1007/s11172-020-2872-x