Reactivity of 1-allylsilatrane in ruthenium-catalyzed silylative coupling with olefins – mechanistic considerations

Abstract We have developed a new effective route for obtaining (E)-vinyl-substituted silatranes via ruthenium-catalyzed silylative coupling of 1-allylsilatrane with olefins. Experimental research allowed us also to propose the mechanism of the process based on stoichiometric reactions.

Bibliographic Details

Published in:	Heterocyclic Communications 2020-01, Vol.26 (1), p.33-36
Main Authors:	Sztorch, Bogna, Frąckowiak, Dawid, Marciniec, Bogdan
Format:	Article
Language:	eng
Subjects:	Alkenes Coupling Ruthenium
Online Access:	Get full text
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