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Kinetics of the Oxidation of Protocatechuic and Gallic Acids by Atmospheric Oxygen in the Presence of Laccase from T. versicolor
The oxidation of 3,4-dihydroxybenzoic and 3,4,5-trihydroxybenzoic acids by atmospheric oxygen in the presence of laccase from T. versicolor is studied via electronic absorption spectroscopy. The molar extinction coefficients of intermediate and final products, the rate constants, and the initial rat...
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Published in: | Russian Journal of Physical Chemistry A 2020-02, Vol.94 (2), p.294-300 |
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Main Authors: | , , , , , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | The oxidation of 3,4-dihydroxybenzoic and 3,4,5-trihydroxybenzoic acids by atmospheric oxygen in the presence of laccase from
T. versicolor
is studied via electronic absorption spectroscopy. The molar extinction coefficients of intermediate and final products, the rate constants, and the initial rates of oxidation are determined by means of the maximum likelihood approach. The parameters of the Michaelis–Menten equation are calculated. Polymeric oxidation products are isolated, and their composition is investigated via mass spectrometry and
13
C NMR spectroscopy. |
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ISSN: | 0036-0244 1531-863X |
DOI: | 10.1134/S0036024420020119 |