Efficient Synthesis of Phenoxathiines via the Cascade C–H Hydroxylation–C–S Coupling–C–O Cyclization Reaction

The ligand-free and simple cascade C–H hydroxylation–C–S coupling–C–O cyclization reaction has been used as the synthetic approach to disulfides and o -chloro-iodobenzenes using CuI as a catalyst. This approach provides an easy and convenient method of synthesis of phenoxathiin derivatives....

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Bibliographic Details
Published in:Russian journal of general chemistry 2019-12, Vol.89 (12), p.2558-2561
Main Authors: Chao, Fei, Xu, Wen-Heng, Ren, Zhi-Lin, Wang, Long
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Coupling
Heterocyclic compounds
Hydroxylation
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Summary:The ligand-free and simple cascade C–H hydroxylation–C–S coupling–C–O cyclization reaction has been used as the synthetic approach to disulfides and o -chloro-iodobenzenes using CuI as a catalyst. This approach provides an easy and convenient method of synthesis of phenoxathiin derivatives.
ISSN:1070-3632
1608-3350
DOI:10.1134/S1070363219120351