Inhibitor loaded calcium carbonate microparticles for corrosion protection of epoxy-coated carbon steel

pH-sensitive calcium carbonate microparticles were loaded with polyethyleneimine (PEI), a corrosion inhibitor, and used as anti-corrosion additive in epoxy coatings applied on carbon steel. The presence of PEI in the CaCO3 particles was confirmed by Fourier-Transform Infra-Red Spectroscopy (FTIR) an...

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Bibliographic Details
Published in:Electrochimica acta 2019-10, Vol.319, p.801-812
Main Authors: Raj, Roma, Morozov, Y., Calado, L.M., Taryba, M.G., Kahraman, R., Shakoor, A., Montemor, M.F.
Format: Article
Language:English
Subjects:
Calcium carbonate
Carbon steel
Carbon steels
Carbon-epoxy composites
Coated electrodes
Corrosion
Corrosion effects
Corrosion inhibitors
Corrosion prevention
Corrosion protection
Electrochemical impedance spectroscopy
Fourier transforms
Functional coating
Gravimetric analysis
Microparticles
PEI
Polyethyleneimine
Protective coatings
Repair & maintenance
Self-healing
Spectrum analysis
Thermal analysis
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Summary:pH-sensitive calcium carbonate microparticles were loaded with polyethyleneimine (PEI), a corrosion inhibitor, and used as anti-corrosion additive in epoxy coatings applied on carbon steel. The presence of PEI in the CaCO3 particles was confirmed by Fourier-Transform Infra-Red Spectroscopy (FTIR) and the loading was quantified by Thermal Gravimetric Analysis (TGA). The protective performance of the modified coatings applied on carbon steel was investigated by Electrochemical Impedance Spectroscopy (EIS) and the results evidenced that the modified coatings provided high corrosion protection and very stable barrier properties over time. The self-healing ability was investigated by Localized Electrochemical Impedance Spectroscopy (LEIS) and by the Scanning Vibrating Electrode Technique (SVET) on coated samples artificially damaged and immersed in NaCl solutions. The results revealed an important corrosion inhibition effect, stable over time, in the coatings modified with the PEI loaded particles. The corrosion inhibition effect involves the dissolution of the calcium carbonate microparticles in the local acid media formed at the anodic sites and subsequent release of the corrosion inhibitor that forms a protective film on the steel surface. [Display omitted] •Nanostructured pH sensitive CaCO3 particles were successfully loaded with Polyethyleneimine (PEI).•Electrochemical impedance spectroscopy demonstrated the high compatibility of the PEI loaded particles with epoxy coatings.•Localized electrochemical tests in presence of defects evidenced corrosion healing ability.
ISSN:0013-4686
1873-3859
DOI:10.1016/j.electacta.2019.07.059