Impact of fabrication temperature on the stability of yttria doped bismuth oxide ceramics

Bi2O3 doped with Y2O3 in the cubic-δ structure is a promising electrolyte material to bring the operating temperatures of solid oxide fuel cells (SOFCs) down to ≤650 °C. However, even in the doped state, the stability of its fast-ionic conductor phase (cubic-δ) at this targeted operating temperature...

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Bibliographic Details
Published in:Solid state ionics 2019-10, Vol.338, p.66-73
Main Authors: Ayhan, Yavuz Selim, Buyukaksoy, Aligul
Format: Article
Language:English
Subjects:
Bismuth oxides
Bismuth trioxide
Ceramics
Conductivity
Conductivity decay
Conductors
Decay rate
Electrical resistivity
Electrolytes
Electrolytic cells
Operating temperature
Phase diagrams
Phase stability
Phase transitions
Production costs
Sintering
Solid oxide fuel cell
Solid oxide fuel cells
Stability
Temperature effects
Yttria doped bismuth oxide
Yttrium oxide
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Summary:Bi2O3 doped with Y2O3 in the cubic-δ structure is a promising electrolyte material to bring the operating temperatures of solid oxide fuel cells (SOFCs) down to ≤650 °C. However, even in the doped state, the stability of its fast-ionic conductor phase (cubic-δ) at this targeted operating temperature is questionable. In this work, the stability of the electrical conductivity of 28 mol% Y2O3 doped Bi2O3 (YDB) ceramics sintered at different temperatures was investigated. YDB ceramics sintered at 800 °C exhibited a fast, exponential-type conductivity decay with a concomitant cubic to rhombohedral phase transformation upon a 100-hour exposure to 650 °C, in stagnant air. On the other hand, all the YDB ceramics sintered at higher temperatures (900–1100 °C) experienced a slower, linear conductivity decay under the same conditions, but with no observable phase transformation. This difference was explained in the premise that, based on the most recent Y2O3-Bi2O3 phase diagram, YDB sintered at 800 °C had a higher amount of metastable cubic-δ phase than those sintered at higher temperatures. Practically, it was suggested that for SOFC applications, the conventional approach of lowering the sintering temperature to reduce the manufacturing costs would result in poor stability in YDB electrolytes. •Yttria doped bismuth oxide (YDB) may be densified upon sintering at 800–1100 °C.•Low-temperature sintering results in high amounts of metastable cubic phase•YDB sintered at 800 °C exhibits a fast, exponential conductivity decay at 650 °C.•YDB sintered at 900–1100 °C a slower, linear conductivity decay at 650 °C
ISSN:0167-2738
1872-7689
DOI:10.1016/j.ssi.2019.05.013