MMZNiY-Catalyzed Tsuji–Trost Type of Reaction: A Selective Mono/Bis Allylation of Dicarbonyl Compounds

An alternative method to Pd-catalyzed Tsuji–Trost reaction is developed and it provides a simpler route for the selective synthesis of a broad range of mono -/ bis -allylated and cinnamylated 1,3-dicarbonyl compounds using MMZ NiY catalyst at room temperature. Product selectivity can be controlled b...

Full description

Saved in:
Bibliographic Details
Published in:Catalysis letters 2017-11, Vol.147 (11), p.2755-2763
Main Authors: Senthilkumar, Samuthirarajan, Thangapriya, Cheirmakani, Alagumurugayee, Raman, Kumarraja, Mayilvasagam
Format: Article
Language:English
Subjects:
Allyl compounds
Carbonyl compounds
Catalysis
Catalysts
Chemical reactions
Chemistry
Chemistry and Materials Science
Industrial Chemistry/Chemical Engineering
Organometallic Chemistry
Physical Chemistry
Route selection
Selectivity
X ray analysis
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:An alternative method to Pd-catalyzed Tsuji–Trost reaction is developed and it provides a simpler route for the selective synthesis of a broad range of mono -/ bis -allylated and cinnamylated 1,3-dicarbonyl compounds using MMZ NiY catalyst at room temperature. Product selectivity can be controlled by the proper choice of catalyst. The catalyst was also well characterized by SEM, TEM, HRTEM, EDAX and X-ray analysis. Other advantages of catalyst like its ease of preparation, functional tolerance and its reusability are also highlighted. Graphical Abstract
ISSN:1011-372X
1572-879X
DOI:10.1007/s10562-017-2185-3