Loading…
Graphene oxide/cross-linked polyimide (GO/CLPI) composite membranes for organic solvent nanofiltration
•The compacted sponge-like structure was obtained via adjusting additive ratio.•The optimum cross-linker was screened to improve the stability.•High permeability was achieved via adjusting the coating conditions.•The LF-NMR technique was utilized to assess the affinity and stability. Purification an...
Saved in:
Published in: | Chemical engineering research & design 2019-06, Vol.146, p.182-189 |
---|---|
Main Authors: | , , , , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
Summary: | •The compacted sponge-like structure was obtained via adjusting additive ratio.•The optimum cross-linker was screened to improve the stability.•High permeability was achieved via adjusting the coating conditions.•The LF-NMR technique was utilized to assess the affinity and stability.
Purification and recovery of polar organic solvents such as dimethylformamide (DMF) with high chemical separation speed and low energy cost nanofiltration membranes has been widely investigated, while it is still a difficult challenge that high permeability of solvents and rejection of solutes are achieved simultaneously. In this study, a novel organic solvent nanofiltration (OSN) membranes was obtained via coating a thin selective graphene oxide (GO) layer on top of the polyimide porous substrate (PI) which was cross-linked to improve the stability in polar solvents. The resultant GO/cross-linked PI (GO/CLPI) composite membranes feature remarkable sieving capability of >94% for RBss molecules (1018 Da), accompanying high pure solvent permeability of 11.1 L h−1 m−2 bar−1, 4.9 L h−1 m−2 bar−1 and 1.0 L h−1 m−2 bar−1 for water, IPA and DMF, respectively. Different from conventional method of characterization, low field nuclear magnetic resonance technology (LF-NMR) was utilized to confirm that the GO/CLPI membrane shows a higher adsorption capacity for IPA than DMF. This newly technique can be effectively utilized to evaluate the affinity between organic solvents and the surface of membranes. |
---|---|
ISSN: | 0263-8762 1744-3563 |
DOI: | 10.1016/j.cherd.2019.03.041 |