Encapsulation and removal of aniline by di-cyclohexanocucurbit[6]uril

This research investigated the binding behaviors of hosts symmetrical di-cyclohexanocucurbit[6]uril (Cy2Q[6]) and hexa-cyclohexanocucurbit[6]uril (Cy6Q[6]) with guests aniline, p -methylaniline, and p -phenyldiamine. 1 H NMR data suggest that hosts Cy2Q[6] and Cy6Q[6] can accommodate all guests to f...

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Bibliographic Details
Published in:New journal of chemistry 2019, Vol.43 (3), p.1487-1493
Main Authors: Zhang, Mingli, Shi, Hao, Meng, Di, Chen, Kai, Lin, Rui-Lian, Sun, Wen-Qi, Liu, Jing-Xin
Format: Article
Language:English
Subjects:
Aniline
Aqueous solutions
Aromatic compounds
Crystallography
Encapsulation
Entrapment
Inclusion complexes
NMR
Nuclear magnetic resonance
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Summary:This research investigated the binding behaviors of hosts symmetrical di-cyclohexanocucurbit[6]uril (Cy2Q[6]) and hexa-cyclohexanocucurbit[6]uril (Cy6Q[6]) with guests aniline, p -methylaniline, and p -phenyldiamine. 1 H NMR data suggest that hosts Cy2Q[6] and Cy6Q[6] can accommodate all guests to form stable inclusion complexes in aqueous solution. X-ray crystallography provides unequivocal evidence that Cy2Q[6] forms inclusion complexes in the solid state with all guests, in which the aromatic rings of the guests are encapsulated. Most importantly, entrapment tests and thermogravimetric analyses show that the Cy2Q[6] host possesses higher removal efficiency for aniline than the Cy6Q[6] host. All results show that the Cy2Q[6] host is more suitable for the recognition and encapsulation of the studied guests than the Cy6Q[6] host because its size and shape are more complementary to the aromatic rings of the guests. Our study suggests the potential utility of Cy2Q[6] as an adsorbent for aniline removal.
ISSN:1144-0546
1369-9261
DOI:10.1039/C8NJ05298K