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Comprehensive elucidation of crystal structures of lithium-intercalated graphite
Graphite is widely used as an anode material in almost all Lithium (Li)-ion batteries. Li is easily absorbed into the layer structure of graphite, forming lithium-carbon intercalation compounds LixC between LiC6 and C. However, although they are simple binary compounds, their structures have been le...
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Published in: | Carbon (New York) 2019-02, Vol.142, p.513-517 |
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Main Authors: | , , , , , , , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | Graphite is widely used as an anode material in almost all Lithium (Li)-ion batteries. Li is easily absorbed into the layer structure of graphite, forming lithium-carbon intercalation compounds LixC between LiC6 and C. However, although they are simple binary compounds, their structures have been left unelucidated for a long time, especially for the compounds between LiC12 and C. This is probably because the Li concentrations are too low to make a big difference in diffraction pattern between these Li-intercalated graphites and pure graphite. It has been known, however, that they have stacked layer structures, which strongly suggests that they are very likely to form modulated structures. Structural analyses of these compounds based on the modulated structure model were successfully performed, comprehensively elucidating all the LixC structures lying between LiC6 and C.
Our structural investigation of LixC crystals confirmed that LiC6 and LiC12 structures coexist between LiC6 (SOC:100%) and LiC12 (SOC:50%); however, we provided the first ever clarification that, between LiC12 (SOC:50%) and C (SOC:0%), Li atom disordering and structural modulation take place in their crystals. [Display omitted] |
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ISSN: | 0008-6223 1873-3891 |
DOI: | 10.1016/j.carbon.2018.10.071 |