Structural, optical and magnetic properties of Co doped ZnO DMS nanoparticles by microwave irradiation method

[Display omitted] •Cobalt (x = 0.001–0.004) doped ZnO nanoparticles are successfully synthesized by microwave irradiation method.•The oxygen related defect is confirmed from PL and ESR studies.•The oxygen mediated exchange interaction could be responsible for the observed ferromagnetism.•The super p...

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Bibliographic Details
Published in:Journal of magnetism and magnetic materials 2018-04, Vol.452, p.335-342
Main Authors: Guruvammal, D., Selvaraj, S., Meenakshi Sundar, S.
Format: Article
Language:English
Subjects:
Blue shift
Carrier density
Co doped ZnO nanoparticles
Cobalt
Crystal defects
Dependence
DMS
Emission analysis
Emission spectra
ESR
Ferromagnetism
Functional groups
Irradiation
Lattice vacancies
Magnetic properties
Magnetism
Microwave irradiation method
Nanoparticles
Optical properties
Oxygen ions
RTFM
Structural analysis
Zinc oxide
Zinc oxides
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Summary:[Display omitted] •Cobalt (x = 0.001–0.004) doped ZnO nanoparticles are successfully synthesized by microwave irradiation method.•The oxygen related defect is confirmed from PL and ESR studies.•The oxygen mediated exchange interaction could be responsible for the observed ferromagnetism.•The super paramagnetic nature may be due to the weakly coupled Co ions in the Zn2+ site in the ZnO lattice•For x = 0.004, the ferromagnetic behavior arises due to the incorporation of Co2+ ions in the interstitial position. Microwave irradiation method is employed to synthesis of Zn1−xCoxO (x = 0.001–0.004) nanoparticles and investigate their structural, optical and magnetic properties using various characterization techniques. Structural studies reveal single phase hexagonal structure with average crystallite size 18–28 nm. FTIR study identifies the functional group present in the samples. The incorporation of Co2+ ions into the ZnO lattice is confirmed through XRD and UV–Vis studies. PL spectra exhibit a strong emission peak in UV region and a defect related visible emission peak in orange red region. These peaks are attributed to near band edge emission and the presence of oxygen related defects in the samples respectively. The blue shift observed in the UV emission peak shows an increase in the carrier concentration caused by the interstitial incorporation of ions into the ZnO lattice. The oxygen related defect is also confirmed through a peak obtained around g factor 1.9933 in ESR studies. Further, the number of spin contributing the ESR signal demonstrates the dependence of the strength of ferromagnetism on the concentration of oxygen ion vacancies. The VSM, ESR and PL measurements confirm the origin of RTFM of Co doped ZnO nanoparticles from the exchange interaction between the localized spin moments resulting from oxygen vacancies. The reason for the obtained super paramagnetic nature for x = 0.002 and x = 0.003 may be either due to some of nanoparticles or due to the weakly coupled Co ions in the Zn2+ site in the ZnO lattice. Further, the ferromagnetic behavior arises again for x = 0.004 due to the incorporation of Co2+ ions in the interstitial positions.
ISSN:0304-8853
1873-4766
DOI:10.1016/j.jmmm.2017.12.097