Selective synthesis of 2,5-bis(aminomethyl)furan via enhancing the catalytic dehydration–hydrogenation of 2,5-diformylfuran dioxime

2,5-Bis(aminomethyl)furan as a promising monomer was efficiently synthesized in 94.1% yield from biomass-derived 2,5-diformylfuran dioxime. The high selectivity is likely to be a result of the controlled reaction pathway over Rh/HZSM-5, which enhanced the sequence of the dehydration–hydrogenation of...

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Bibliographic Details
Published in:Green chemistry : an international journal and green chemistry resource : GC 2018, Vol.20 (12), p.2697-2701
Main Authors: Xu, Yongming, Jia, Xiuquan, Ma, Jiping, Gao, Jin, Xia, Fei, Li, Xiaofang, Xu, Jie
Format: Article
Language:English
Subjects:
Acidity
Catalysis
Chemical synthesis
Dehydration
Green chemistry
Hydrogenation
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Summary:2,5-Bis(aminomethyl)furan as a promising monomer was efficiently synthesized in 94.1% yield from biomass-derived 2,5-diformylfuran dioxime. The high selectivity is likely to be a result of the controlled reaction pathway over Rh/HZSM-5, which enhanced the sequence of the dehydration–hydrogenation of 2,5-diformylfuran dioxime owing to the surface acidity on the HZSM-5 support.
ISSN:1463-9262
1463-9270
DOI:10.1039/C8GC00947C