Poly[[[mu]-aqua-bis­([mu]-2,4-dichloro­phen­oxy­acetato)barium(II)] monohydrate]

In the title coordination polymer, {[Ba(C8H5Cl2O3)2(H2O)]dotH2O}n, each BaII atom is nine-coordinated by six carboxylate O atoms and one ether O atom from five symmetry-related 2,4-dichlorophenoxyacetate ligands, and by two O atoms from water molecules, thus defining a distorted tricapped trigonal p...

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Bibliographic Details
Published in:Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2006-11, Vol.62 (11), p.m516
Main Authors: Chang-Sheng, Gu, Xiao-Min, Hao, Shu-Xia Guan, Ji-Wei, Liu
Format: Article
Language:English
Subjects:
Crystal structure
Hydrogen bonds
Polymers
Water
Online Access:Get full text
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Summary:In the title coordination polymer, {[Ba(C8H5Cl2O3)2(H2O)]dotH2O}n, each BaII atom is nine-coordinated by six carboxylate O atoms and one ether O atom from five symmetry-related 2,4-dichlorophenoxyacetate ligands, and by two O atoms from water molecules, thus defining a distorted tricapped trigonal prism. The BaII ions are bridged by bidentate water molecules and by tridentate and tetradentate 2,4-dichlorophenoxyacetate groups, leading to a two-dimensional layer structure. The crystal structure is further stabilized by hydrogen-bonding interactions within each layer. [PUBLICATION ABSTRACT]
ISSN:0108-2701
1600-5759
DOI:10.1107/S0108270106037565