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Yellow laser potential of cubic Ca^sub 3^(Nb,Ga)^sub 5^O^sub 12^:Dy^sup 3+^ and Ca^sub 3^(Li,Nb,Ga)^sub 5^O^sub 12^:Dy^sup 3+^ single crystals
Spectroscopic investigation of Dy3+ doped Ca3(Nb,Ga)5O12 (CNGG) and Ca3(Li,Nb,Ga)5O12 (CLNGG) single crystals were performed in order to assess their potential as laser materials for yellow emission. Dy:CNGG and Dy:CLNGG single crystals were grown by the Czochralski method and investigated by high-r...
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Published in: | Journal of alloys and compounds 2018-03, Vol.739, p.806 |
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Main Authors: | , , , , , , , , |
Format: | Article |
Language: | English |
Subjects: | |
Online Access: | Get full text |
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Summary: | Spectroscopic investigation of Dy3+ doped Ca3(Nb,Ga)5O12 (CNGG) and Ca3(Li,Nb,Ga)5O12 (CLNGG) single crystals were performed in order to assess their potential as laser materials for yellow emission. Dy:CNGG and Dy:CLNGG single crystals were grown by the Czochralski method and investigated by high-resolution spectroscopic measurements for the first time. The Judd-Ofelt intensity parameters for the f-f transitions of Dy3+ in CNGG and CLNGG single crystals, were used to determine radiative transition rates Ar, branching ratios β, and radiative lifetime Γr of the fluorescent Dy3+ levels. Based on low temperature absorption and emission spectra, partial energy levels diagram of Dy3+ doped CNGG and CLNGG single crystals were obtained. The emission cross-sections for the 4F9/2 → 6H13/2 transition of special interest for laser application were determined. The room temperature decay curves were analyzed through the framework of Inokuti-Hirayama (I-H) model and the results shows that electric dipole-dipole interaction are responsible for the energy transfer processes between Dy3+ ions in CNGG and CLNGG single crystals. |
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ISSN: | 0925-8388 1873-4669 |