Template-free synthesis of highly ordered 3D-hollow hierarchical Nb2O5 superstructures as an asymmetric supercapacitor by using inorganic electrolyte

•A novel hollow hierarchical orthorhombic Nb2O5 synthesized by one pot method.•An asymmetric supercapacitor fabricated by NHH-T-Nb2O5.•the device exhibits high power density (650W/Kg), energy density (86Wh/Kg).•The device is operated at a wide voltage window of 2.5V in an aqueous electrolyte. Nb2O5...

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Bibliographic Details
Published in:Electrochimica acta 2016-10, Vol.216, p.332-338
Main Authors: Idrees, Faryal, Hou, Jianhua, Cao, Chuanbao, Butt, Faheem K., Shakir, Imran, Tahir, Muhammad, Idrees, Farwa
Format: Article
Language:English
Subjects:
Band gap
Crystallinity
Electrolytes
Flux density
Hierarchical
Hollow
Hydrothermal
Niobium oxides
Nuclear electric power generation
Nucleation
Semiconductors
Supercapacitor
Supercapacitors
Superstructures
Synthesis
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Summary:•A novel hollow hierarchical orthorhombic Nb2O5 synthesized by one pot method.•An asymmetric supercapacitor fabricated by NHH-T-Nb2O5.•the device exhibits high power density (650W/Kg), energy density (86Wh/Kg).•The device is operated at a wide voltage window of 2.5V in an aqueous electrolyte. Nb2O5 appeared as a promising candidate for a large number of applications. In the present work novel, 3D-hollow hierarchical Nb2O5 superstructures are prepared by self-organization of mesorods. The work emphasizes on the synthesis and detailed investigation of 3D-hollow hierarchical Nb2O5 superstructures, which are attained by two-step, template-free hydrothermal synthesis route. The obtained orthorhombic(T)-Nb2O5 superstructures have shown a high crystallinity, with a wide band gap of 3.1eV. Among semiconductor oxides Nb2O5 with different morphologies are less explored due to complicated synthesis, growth and nucleation process. Thus, in general, factors involved for self-organized superstructures are not studied in detail. In this context, assembly of T-Nb2O5 superstructures is investigated in depth by applying SEM, TEM and UV/Vis absorption measurements. Based on the realized results a formation mechanism is proposed, which is further strengthened by the time and precursor dependent experiments. In addition, asymmetric supercapacitor properties of T-Nb2O5 superstructures are studied for the first time by using an inorganic electrolyte. The devised T-Nb2O5 superstructures have demonstrated excellent supercapacitor performance. The supercapacitor is operated at a wide potential window of 2.5V in Na2SO4 electrolyte and exhibited high power density (650W/Kg), energy density (86Wh/Kg) with good cycling capability.
ISSN:0013-4686
1873-3859
DOI:10.1016/j.electacta.2016.09.031