Effect of melt spinning on gaseous hydrogen storage characteristics of nanocrystalline and amorphous Nd-added Mg2Ni-type alloys

Nanocrystalline and amorphous Mg-Nd-Ni-Cu quaternary alloys with a composition of (Mg 24 Ni 10 Cu 2 ) 100- x Nd x ( x =0, 5, 10, 15, 20) were prepared by melt spinning technology and their structures as well as gaseous hydrogen storage characteristics were investigated. The XRD, TEM and SEM linked w...

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Bibliographic Details
Published in:Journal of Central South University 2016-11, Vol.23 (11), p.2754-2762
Main Authors: Zhang, Yang-huan, Yuan, Ze-ming, Yang, Tai, Qi, Yan, Guo, Shi-hai, Zhao, Dong-liang
Format: Article
Language:English
Subjects:
Chemical and Environmental Engineering
Engineering
Hydrogen storage
Hydrogen storage materials
Materials
Melt spinning
Metallic Materials
Metallurgy
Nanocrystals
Quaternary alloys
Thermal stability
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Summary:Nanocrystalline and amorphous Mg-Nd-Ni-Cu quaternary alloys with a composition of (Mg 24 Ni 10 Cu 2 ) 100- x Nd x ( x =0, 5, 10, 15, 20) were prepared by melt spinning technology and their structures as well as gaseous hydrogen storage characteristics were investigated. The XRD, TEM and SEM linked with EDS detections reveal that the as-spun Nd-free alloy holds an entire nanocrystalline structure but a nanocrystalline and amorphous structure for the as-spun Nd-added alloy, implying that the addition of Nd facilitates the glass forming in the Mg 2 Ni-type alloy. Furthermore, the degree of amorphization of the as-spun Nd-added alloy and thermal stability of the amorphous structure clearly increase with the spinning rate rising. The melt spinning ameliorates the hydriding and dehydriding kinetics of the alloys dramatically. Specially, the rising of the spinning rate from 0 (the as-cast was defined as the spinning rate of 0 m/s) to 40 m/s brings on the hydrogen absorption saturation ratio ( R 5 a ) (a ratio of the hydrogen absorption quantity in 5 min to the saturated hydrogen absorption capacity) increasing from 36.9% to 91.5% and the hydrogen desorption ratio ( R 10 d ) (a ratio of the hydrogen desorption quantity in 10 min to the saturated hydrogen absorption capacity) rising from 16.4% to 47.7% for the ( x =10) alloy, respectively.
ISSN:2095-2899
2227-5223
DOI:10.1007/s11771-016-3337-0