Study towards diversity oriented synthesis of optically active substituted cyclopentane fused carbocyclic and oxacyclic medium-sized rings: Competition between Grubbs-II catalyzed ring closing olefin metathesis and ring closing carbonyl-olefin metathesis

A study towards diversity-oriented synthesis of optically active cyclopentane fused bicyclic frameworks has been accomplished. The common intermediate was prepared from commercially available starting material ( S )-carvone. The observations on competition between Grubbs-II catalyzed ring closing me...

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Bibliographic Details
Published in:Journal of chemical sciences (Bangalore, India) India), 2016-12, Vol.128 (12), p.1831-1840
Main Authors: CHAKRABORTY, P, ROY, S C
Format: Article
Language:English
Subjects:
Carbonyls
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Competition
Decomposition reactions
Metathesis
Optical activity
Synthesis
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Summary:A study towards diversity-oriented synthesis of optically active cyclopentane fused bicyclic frameworks has been accomplished. The common intermediate was prepared from commercially available starting material ( S )-carvone. The observations on competition between Grubbs-II catalyzed ring closing metathesis (RCM) and ring closing carbonyl-olefin metathesis (RCCOM) were the key features of the study. Graphical Abstract A study towards diversity-oriented synthesis of optically active cyclopentane fused bicyclic frameworks has been accomplished. The observations on competition between Grubbs-II catalyzed ring closing metathesis (RCM) and ring closing carbonyl-olefin metathesis (RCCOM) were the key features of the study.
ISSN:0974-3626
0973-7103
DOI:10.1007/s12039-016-1197-7