CpFe(CO)2TePh as a ligand for organometallic dihalides Fe(CO)4I2, (p-Cymene)RuI2, and Me5C5RhI2: Synthesis and molecular structures

CpFe(CO) 2 TePh ( I ) can substitute one carbonyl group in Fe(CO) 4 I 2 providing Fe(CO) 3 I 2 (μ-TePh)Fe(CO) 2 Cp ( II ) or play role of ligand to monomeric fragments [( p -Cymene)RuI 2 ] and [Сp*RhI 2 ] ( p -Cymene = (η 6 -1-isopropyl-4-methylbenzene); Сp* = η 5 -pentamethylcyclopentadienyl) provi...

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Bibliographic Details
Published in:Russian journal of coordination chemistry 2017, Vol.43 (1), p.44-49
Main Authors: Pasynskii, A. A., Skabitskiy, I. V., Torubaev, Yu. V., Pavlova, A. V., Shapovalov, S. S., Tikhonova, O. G., Sakharov, S. G.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Inorganic Chemistry
Ligands
Molecular structure
Monomers
Physical Chemistry
Single crystals
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Summary:CpFe(CO) 2 TePh ( I ) can substitute one carbonyl group in Fe(CO) 4 I 2 providing Fe(CO) 3 I 2 (μ-TePh)Fe(CO) 2 Cp ( II ) or play role of ligand to monomeric fragments [( p -Cymene)RuI 2 ] and [Сp*RhI 2 ] ( p -Cymene = (η 6 -1-isopropyl-4-methylbenzene); Сp* = η 5 -pentamethylcyclopentadienyl) provides the complexes ( p -Cymene)RuI 2 (μ-TePh)Fe(CO) 2 Cp (III) and Cp*RhCl 2 (μ-TePh)Fe(CO) 2 Cp ( IV ), respectively. The single-crystal X-ray diffraction of complexes II–IV (CIF files CCDC nos. 1038124 ( II ), 1038127 ( III ), 1038125 ( IV )) revealed the shortening of М–Те bonds and the presence of intramolecular I…Te contacts.
ISSN:1070-3284
1608-3318
DOI:10.1134/S1070328417010067