Understanding the Degradation Mechanisms of LiNi0.5Co0.2Mn0.3O2 Cathode Material in Lithium Ion Batteries

LiNixCoyMnzO2 (NCM, 0 ≤ x,y,z < 1) has become one of the most important cathode materials for next‐generation lithium (Li) ion batteries due to its high capacity and cost effectiveness compared with LiCoO2. However, the high‐voltage operation of NCM (>4.3 V) required for high capacity is inevi...

Full description

Saved in:
Bibliographic Details
Published in:Advanced energy materials 2014-01, Vol.4 (1), p.1-n/a
Main Authors: Jung, Sung-Kyun, Gwon, Hyeokjo, Hong, Jihyun, Park, Kyu-Young, Seo, Dong-Hwa, Kim, Haegyeom, Hyun, Jangsuk, Yang, Wooyoung, Kang, Kisuk
Format: Article
Language:English
Subjects:
cathode materials
degradation mechanisms
layered structures
Lithium
lithium ion battery
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:LiNixCoyMnzO2 (NCM, 0 ≤ x,y,z < 1) has become one of the most important cathode materials for next‐generation lithium (Li) ion batteries due to its high capacity and cost effectiveness compared with LiCoO2. However, the high‐voltage operation of NCM (>4.3 V) required for high capacity is inevitably accompanied by a more rapid capacity fade over numerous cycles. Here, the degradation mechanisms of LiNi0.5Co0.2Mn0.3O2 are investigated during cycling under various cutoff voltage conditions. The surface lattice structures of LiNi0.5Co0.2Mn0.3O2 are observed to suffer from an irreversible transformation; the type of transformation depends on the cutoff voltage conditions. The surface of the pristine rhombohedral phase tends to transform into a mixture of spinel and rock salt phases. Moreover, the formation of the rock salt phase is more dominant under a higher voltage operation (≈4.8 V), which is attributable to the highly oxidative environment that triggers the oxygen loss from the surface of the material. The presence of the ionically insulating rock salt phase may result in sluggish kinetics, thus deteriorating the capacity retention. This implies that the prevention of surface structural degradation can provide the means to produce and retain high capacity, as well as stabilize the cycle life of LiNi0.5Co0.2Mn0.3O2 during high‐voltage operations. The degradation mechanisms of LiNi0.5Co0.2Mn0.3O2 are investigated during cycling under high voltage conditions. The results indicate that the structural degradation occurs mainly on the surface of the materials where the phase transformation from rhombohedral to spinel is dominant. However, depending on the cutoff voltage, the formation of the rock salt phase can also occur, which is suspected to increase the charge transfer resistance
ISSN:1614-6832
1614-6840
DOI:10.1002/aenm.201300787