Regiospecific silver[I] promoted, palladium[O]-catalyzed intramolecular addition of aryl iodides to vinyl sulfones

Treatment of aryl iodides with 5% tetrakis(triphenylphosphine)palladium[O] in the presence of silver nitrate and triethylamine in acetonitrile at reflux effects intramotecular conjugate-addition/reductive elimination to generate an annulated vinyl sulfone. Omission of the silver nitrate produces mix...

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Bibliographic Details

Published in:	Tetrahedron letters 1993-08, Vol.34 (33), p.5205-5208
Main Authors:	Jin, Zhendong, Fuchs, P.L.
Format:	Article
Language:	English
Subjects:	Chemistry Exact sciences and technology Heterocyclic compounds Heterocyclic compounds with o, s, se, te hetero atom and condensed derivatives Organic chemistry Preparations and properties
Online Access:	Get full text
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