Characterization of Al Cu and Al Cu Mg mixed oxides and their catalytic activity in dehydrogenation of 2-octanol

Hydrotalcite (HT) type materials with different Cu:Mg:Al ratios were prepared. The samples were calcined at 450 °C and when the layered structure was destroyed mixed oxides were formed. Such oxides were reduced under a flow of hydrogen gas at 300 °C and their catalytic activity in dehydrogenation of...

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Bibliographic Details
Published in:Catalysis today 2005-10, Vol.107, p.215-222
Main Authors: Crivello, Mónica, Pérez, Celso, Herrero, Eduardo, Ghione, Guillermo, Casuscelli, Sandra, Rodríguez-Castellón, Enrique
Format: Article
Language:English
Subjects:
Alcohols dehydrogenation
Catalysis
Chemistry
Exact sciences and technology
General and physical chemistry
Hydrotalcites
Layered double hydroxides
Mixed oxides
Octanol decomposition
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
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Summary:Hydrotalcite (HT) type materials with different Cu:Mg:Al ratios were prepared. The samples were calcined at 450 °C and when the layered structure was destroyed mixed oxides were formed. Such oxides were reduced under a flow of hydrogen gas at 300 °C and their catalytic activity in dehydrogenation of 2-octanol was studied. High conversion and selectivity towards 2-octanone was observed. The samples without copper showed low conversion, but it increased with the copper content. The characterization of both precursors and reduced catalysts was carried out by XRD, XPS and diffuse reflectance. In the calcined samples, the XPS analysis detected Cu 2+ in a CuAl 2O 4 spinel-like environment as well as CuO, while the reduced samples contained Cu 0 and copper ions, such as Cu 2+ and Cu +. Diffuse reflectance showed that the copper was present in two forms, the perfect and distorted octahedra. In the Al Cu Mg system, the copper was present in a cluster-like or bulk-like species, excepting the samples having a copper excess, where a spinel-like species was detected. By XRD, a greater structural ordering was observed in the samples containing a ratio Cu 2+/Mg 2+ ≤ 1 (Cu < 50% keeping in mind only cations M 2+) and in those having a ratio (M 3+/M 3+ + M 2+) approximately equal to 0.25; in this case other species were not detected.
ISSN:0920-5861
1873-4308
DOI:10.1016/j.cattod.2005.07.168