Structural and vibrational properties of single crystals of Scandia, Sc{sub 2}O{sub 3} under high pressure

We report the results of single-crystal X-ray diffraction and Raman spectroscopy studies of scandium oxide, Sc{sub 2}O{sub 3}, at ambient temperature under high pressure up to 55 and 28 GPa, respectively. Both X-ray diffraction and Raman studies indicated a phase transition from the cubic bixbyite p...

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Bibliographic Details
Published in:Journal of applied physics 2015-10, Vol.118 (16)
Main Authors: Ovsyannikov, Sergey V., Wenz, Michelle D., Pakhomova, Anna S., Dubrovinsky, Leonid, Bykova, Elena, Bykov, Maxim, Laboratory of Crystallography, Universität Bayreuth, Universitätsstrasse 30, D-95447 Bayreuth, Glazyrin, Konstantin, Liermann, Hanns-Peter
Format: Article
Language:English
Subjects:
AMBIENT TEMPERATURE
CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS
MATERIALS SCIENCE
MONOCLINIC LATTICES
MONOCRYSTALS
PHASE TRANSFORMATIONS
PRESSURE RANGE GIGA PA
RAMAN SPECTROSCOPY
SCANDIUM OXIDES
X-RAY DIFFRACTION
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Summary:We report the results of single-crystal X-ray diffraction and Raman spectroscopy studies of scandium oxide, Sc{sub 2}O{sub 3}, at ambient temperature under high pressure up to 55 and 28 GPa, respectively. Both X-ray diffraction and Raman studies indicated a phase transition from the cubic bixbyite phase (so-called C-Res phase) to a monoclinic C2/m phase (so-called B-Res phase) at pressures around 25–28 GPa. The transition was accompanied by a significant volumetric drop by ∼6.7%. In addition, the Raman spectroscopy detected a minor crossover around 10–12 GPa, which manifested in the appearance of new and disappearance of some Raman modes, as well as in softening of one Raman mode. We found the bulk modulus values of the both C-Res and B-Res phases as B{sub 0} = 198.2(3) and 171.2(1) GPa (for fixed B′ = 4), respectively. Thus, the denser high-pressure lattice of Sc{sub 2}O{sub 3} is much softer than the original lattice. We discuss possible mechanisms that might be responsible for the pronounced elastic softening in the monoclinic high-pressure phase in this “simple” oxide with an ultra-wide band gap.
ISSN:0021-8979
1089-7550
DOI:10.1063/1.4933391