Expanding Linker Dimensionality in Metal‐organic Frameworks for sub‐Ångstrom Pore Control for Separation Applications

Metal‐organic frameworks (MOFs) are a class of porous materials with high surface areas, which are acquiring rapid attention on an exponential basis. A significant characteristic of MOFs is their ability to act as adsorbents to selectively separate component mixtures of similar size, thereby address...

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Bibliographic Details
Published in:Angewandte Chemie (International ed.) 2023-07, Vol.62 (28), p.e202304094-n/a
Main Authors: Macreadie, Lauren K., Idrees, Karam B., Smoljan, Courtney S., Farha, Omar K.
Format: Article
Language:English
Subjects:
3D-Linker
Distillation
Metal-Organic Framework
Metal-organic frameworks
Porous materials
Selective Adsorption
Separation
Separations
Sub-Angstrom Control
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Summary:Metal‐organic frameworks (MOFs) are a class of porous materials with high surface areas, which are acquiring rapid attention on an exponential basis. A significant characteristic of MOFs is their ability to act as adsorbents to selectively separate component mixtures of similar size, thereby addressing the technological need for an alternative approach to conventional distillation methods. Recently, MOFs comprising a 3‐Dimensional (3D) linker have shown outstanding capabilities for difficult separations compared to the parent 2‐Dimensional (2D) analogue. 3D‐linkers with a polycyclic core are underrepresented in the MOF database due to the widespread preferred use of 2D‐linkers and the misconceived high‐cost of 3D linkers. We summarize the recent research of 3D‐linker MOFs and highlight their beneficial employment for selective gas and hydrocarbon adsorption and separation. Furthermore, we outline forecasts in this area to create a platform for widespread adoption of 3D‐linkers in MOF synthesis. Increasing linker dimensionality in metal‐organic frameworks limits the effects of linker orientation and structural flexibility on pore size, ultimately enhancing the separation capabilities of these materials.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.202304094