Modeling the performance and faradaic efficiency of solid oxide electrolysis cells using doped barium zirconate perovskite electrolytes

Y-doped BaZrO3 (BaZr1−xYxO3−δ, or “BZY”), a proton-conducting ceramic featuring high bulk conductivity and good chemical stability, is a promising electrolyte material for solid oxide electrolysis cells. Further doping with Ce and/or Yb (creating materials “BCZY” and “BCZYYb”) can improve conductivi...

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Bibliographic Details
Published in:International journal of hydrogen energy 2021-03, Vol.46 (21), p.11511-11522
Main Authors: Wrubel, Jacob A., Gifford, Jeffrey, Ma, Zhiwen, Ding, Hanping, Ding, Dong, Zhu, Tianli
Format: Article
Language:English
Subjects:
08 HYDROGEN
Barium zirconate
BZY
Cerium reduction
Defect transport
Faradaic efficiency
Hydrogen
modeling
Nernst-Planck
perovskite
Solid oxide electrolysis
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Summary:Y-doped BaZrO3 (BaZr1−xYxO3−δ, or “BZY”), a proton-conducting ceramic featuring high bulk conductivity and good chemical stability, is a promising electrolyte material for solid oxide electrolysis cells. Further doping with Ce and/or Yb (creating materials “BCZY” and “BCZYYb”) can improve conductivity and sintering properties, but at significant penalty to cells’ faradaic efficiency (FE). Studies have proposed that reduction of lattice Ce can occur in the hydrogen electrode, which consumes some hydrogen produced by the hydrogen evolution reaction, leading to decreased FE. Despite studies suggesting this phenomenon, the mechanism is largely unknown. We developed a multiphysics model to study the transport of multiple defect species and the performance of BZY, BCZY, and BCZYYb, capturing the tradeoff between enhanced performance at the cost of FE for BCZY and BCZYYb electrolytes compared to BZY. We also found that increasing the water content of the anode gas supply lowers the current output of the cell but results in better FE. The model, which uses several parameters previously unavailable in the literature, was validated to experiments varying temperature, steam water content, and electrolyte material, as well as two performance metrics (performance curves and FE). Results verify and explain observed trends, informing future work on Ce-doped BZY electrolytes. •Developed an electrochemical transport model to simulate defect species and gases.•Doping with Ce leads to higher conductivity but worse faradaic efficiency (FE).•The low FE behavior has been hypothesized to be due to the reduction of lattice Ce.•We proposed a mechanism for the electrochemical reduction of lattice cerium.•Accumulation of H2 in the cathode exacerbates the poor faradaic efficiency.
ISSN:0360-3199
1879-3487
DOI:10.1016/j.ijhydene.2021.01.043