Quantifying the flow efficiency in constant-current capacitive deionization

Here we detail a previously unappreciated loss mechanism inherent to capacitive deionization (CDI) cycling operation that has a substantial role determining performance. This mechanism reflects the fact that desalinated water inside a cell is partially lost to re-salination if desorption is carried...

Full description

Saved in:
Bibliographic Details
Published in:Water research (Oxford) 2018-02, Vol.129 (C), p.327-336
Main Authors: Hawks, Steven A., Knipe, Jennifer M., Campbell, Patrick G., Loeb, Colin K., Hubert, McKenzie A., Santiago, Juan G., Stadermann, Michael
Format: Article
Language:English
Subjects:
Capacitive deionization
Capacitive desalination
CDI
Flow efficiency
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Here we detail a previously unappreciated loss mechanism inherent to capacitive deionization (CDI) cycling operation that has a substantial role determining performance. This mechanism reflects the fact that desalinated water inside a cell is partially lost to re-salination if desorption is carried out immediately after adsorption. We describe such effects by a parameter called the flow efficiency, and show that this efficiency is distinct from and yet multiplicative with other highly-studied adsorption efficiencies. Flow losses can be minimized by flowing more feed solution through the cell during desalination; however, this also results in less effluent concentration reduction. While the rationale outlined here is applicable to all CDI cell architectures that rely on cycling, we validate our model with a flow-through electrode CDI device operated in constant-current mode. We find excellent agreement between flow efficiency model predictions and experimental results, thus giving researchers simple equations by which they can estimate this distinct loss process for their operation. •A new efficiency parameter, defined as the flow efficiency, is modeled and measured.•The flow efficiency is on par with and yet distinct from the traditional CDI charge efficiencies.•Traditional CDI performance metrics are optimized for minimal concentration reduction.
ISSN:0043-1354
1879-2448
DOI:10.1016/j.watres.2017.11.025