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Olefin conversion on nitrogen-doped carbon-supported cobalt catalyst: Effect of feedstock
[Display omitted] •CoOx/N-C dimerized light olefins into mixtures of linear oligomers.•Olefin conversion catalyzed by CoOx/N-C follows a Cossee-Arlman mechanism.•Ethylene oligomerization produced higher linear alpha olefin products.•Both 1-butene and ethylene produced a Schulz-Flory distribution of...
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Published in: | Journal of catalysis 2017-10, Vol.354 (C), p.213-222 |
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Main Authors: | , , , , , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | [Display omitted]
•CoOx/N-C dimerized light olefins into mixtures of linear oligomers.•Olefin conversion catalyzed by CoOx/N-C follows a Cossee-Arlman mechanism.•Ethylene oligomerization produced higher linear alpha olefin products.•Both 1-butene and ethylene produced a Schulz-Flory distribution of oligomers.
A nitrogen-doped carbon-supported cobalt oxide catalyst is able to oligomerize ethylene, propylene, 1-butene and 1-hexene into mixtures of oligomers with above 94.1% dimers. Higher than 72.5% of the dimers produced from 1-butene and 1-hexene are internal linear olefins, while the dimer products from propylene oligomerization are 47.0% linear including 5.9% 1-hexene. Ethylene had the highest oligomerization activity with 56.1–87.0% 1-butene selectivity. The selectivity to linear alpha olefins decreases with an increasing oligomer chain length during ethylene oligomerization. The oligomers formed from ethylene conversion follow a Schulz-Flory distribution. Cossee type mechanism rationalizes the product selectivity from the four olefin feeds, suggesting that a 1,2-2,1 insertion sequence is critical to obtaining linear olefin products. The catalyst was inactive in oligomerizing internal olefins. |
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ISSN: | 0021-9517 1090-2694 |
DOI: | 10.1016/j.jcat.2017.08.019 |