The kinetics of selective oxidation of propene on bismuth vanadium molybdenum oxide catalysts

The oxidation of propene to acrolein on Bi1−x/3V1−xMoxO4 was investigated in a systematic manner to identify the role of composition on catalyst activity and selectivity. The apparent rate coefficient kapp exhibits a maximum for 0

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Bibliographic Details
Published in:Journal of catalysis 2013-12, Vol.308 (C), p.25-36
Main Authors: Zhai, Zheng, Getsoian, Andrew “Bean”, Bell, Alexis T.
Format: Article
Language:English
Subjects:
absorption
Acrolein
bismuth
Bismuth vanadium molybdenum oxide
Catalysis
catalysts
Chemistry
Exact sciences and technology
General and physical chemistry
Kinetics
molybdenum
Oxidation
oxygen
Propene
propylene
Selective oxidation
spectroscopy
surface area
temperature
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
vanadium
X-radiation
X-ray diffraction
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Description
Summary:The oxidation of propene to acrolein on Bi1−x/3V1−xMoxO4 was investigated in a systematic manner to identify the role of composition on catalyst activity and selectivity. The apparent rate coefficient kapp exhibits a maximum for 0
ISSN:0021-9517
1090-2694
DOI:10.1016/j.jcat.2013.05.008